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Stereoselective Synthesis of meso-1,5-Cyclodecadiynes

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posted on 20.11.2009, 00:00 authored by Gagik G. Melikyan, Ryan Spencer, Edwin Abedi
Reduction of Co2(CO)6-stabilized bis-propargyl cations with cobaltocene occurs with high meso-diastereoselectivity (up to 97%), affording, upon decomplexation, meso-1,5-cyclodecadiynes, otherwise hardly accessible.

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