jo901404f_si_002.cif (56.5 kB)

Stereoselective Synthesis of meso-1,5-Cyclodecadiynes

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posted on 2009-11-20, 00:00 authored by Gagik G. Melikyan, Ryan Spencer, Edwin Abedi

Reduction of Co₂(CO)₆-stabilized bis-propargyl cations with cobaltocene occurs with high meso-diastereoselectivity (up to 97%), affording, upon decomplexation, meso-1,5-cyclodecadiynes, otherwise hardly accessible.

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Co cation meso Stereoselective Synthesis decomplexation cobaltocene

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Stereoselective Synthesis of meso-1,5-Cyclodecadiynes

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