ol5b00558_si_006.cif (110.06 kB)
Download file

Stereochemical Studies of the Opening of Chloro Vinyl Epoxides: Cyclic Chloronium Ions as Intermediates

Download (110.06 kB)
posted on 2015-04-17, 00:00 authored by Andrej Shemet, David Sarlah, Erick M. Carreira
A systematic study of the opening of a collection of chlorinated vinyl epoxides is reported, which includes experiments that implicate both five- and four-membered chloronium ions as plausible intermediates in this type of epoxide opening reaction.