Stabilized α-Helix-Catalyzed Enantioselective Epoxidation of α,β-Unsaturated Ketones
datasetposted on 06.08.2010 by Masanobu Nagano, Mitsunobu Doi, Masaaki Kurihara, Hiroshi Suemune, Masakazu Tanaka
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Chiral cyclic α-amino acid containing oligopeptide catalyzed highly enantioselective epoxidation of α,β-unsaturated ketones and the α-helical secondary structure of the peptide catalyst were revealed by X-ray crystallographic analysis.