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Spin-Canting Magnetization in an Unusual Co4 Cluster-Based Layer Compound from a 2,3-Dihydroxyquinoxaline Ligand

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posted on 16.01.2012, 00:00 by Chen-I Yang, Po-Hsiang Chuang, Gene-Hsiang Lee, Shie-Ming Peng, Kuang-Lieh Lu
The self-assembly of Co­(O2CPh)2 with a 2,3-dihydroxyquinoxaline (H2dhq) linker has revealed a new two-dimensional cluster-based compound, [Co4(OMe)2(O2CPh)2(dhq)2(MeOH)2]n, which shows spin-canted magnetization and a definite magnetic hysteresis loop.