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Solvent-Tuned Azido-Bridged Co2+ Layers:  Square, Honeycomb, and Kagomé

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posted on 25.01.2006, 00:00 by Xin-Yi Wang, Lu Wang, Zhe-Ming Wang, Song Gao
Three azido-bridged Co2+ complexes with square, honeycomb, and Kagomé layered structures were synthesized and structurally characterized. Crystallization solvents are found to be critical in generating the observed topologies. These structurally related complexes are of significance in studying two-dimensional antiferromagnetism and geometric frustration.