Size-Selective Vapochromic Platinum(II) Complex with a Sterically Demanding Pincer-Type N-Heterocyclic Carbene Ligand

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posted on 2011-07-25, 00:00 authored by Chen-Shiang Lee, Rui Rui Zhuang, Shahulhameed Sabiah, Ju-Chun Wang, Wen-Shu Hwang, Ivan J. B. Lin

A pyridine-based pincer-type N-heterocyclic carbene complex of Pt(II), [Pt(II)(^mesC^∧N^∧C)CO](PF₆)₂ (^mesC^∧N^∧C = 2,6-bis(1-mestylimidazol-2-ylidenyl)pyridine), displays size-selective vapochromic behavior upon exposure to small molecules with donor atoms. An acetone adduct showing a weak interaction between acetone and a CO ligand is also structurally determined.

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Pt Sterically LigandA Complex vapochromic donor atoms ligand Carbene acetone adduct molecule bi carbene exposure interaction display mesC Vapochromic

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Size-Selective Vapochromic Platinum(II) Complex with a Sterically Demanding Pincer-Type N-Heterocyclic Carbene Ligand

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