Single-Crystal-to-Single-Crystal Postsynthetic Modification of a Metal–Organic Framework via Ozonolysis
dataset
posted on 2018-01-24, 00:00 authored by Jorge Albalad, Heng Xu, Felipe Gándara, Mohamed Haouas, Charlotte Martineau-Corcos, Rubén Mas-Ballesté, Sarah A. Barnett, Judith Juanhuix, Inhar Imaz, Daniel MaspochWe describe solid–gas
phase, single-crystal-to-single-crystal,
postsynthetic modifications of a metal–organic framework (MOF).
Using ozone, we quantitatively transformed the olefin groups of a
UiO-66-type MOF into 1,2,4-trioxolane rings, which we then selectively
converted into either aldehydes or carboxylic acids.
