American Chemical Society
Browse
om100990r_si_001.cif (23.31 kB)

Serendipitous Discovery of a Phosphirene−Phosphindole Rearrangement

Download (23.31 kB)
dataset
posted on 2011-01-24, 00:00 authored by Duanghathai Panichakul, François Mathey
The reaction of strong Lewis acids with 2-amino-3-phenylphosphirene pentacarbonyltungsten complexes leads to the corresponding 2-aminophosphindoles through the unexpected formation of a bond between phosphorus and one of the ortho carbons of the phenyl ring.

History