cg025573x_si_002.cif (44.57 kB)

Self-Assembly of Discrete Organometallic−Organic Hybrid Supramolecular Arrays from Ferrocenyl Dipyridines and Terephthalic and Trimesic Acids

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posted on 27.09.2002, 00:00 by Dong Mok Shin, Young Keun Chung, In Su Lee
Reactions of ferrocenyl dipyridines (1a,b) with terephthalic (2) and trimesic acid (4) form [2+2] and [3+2] supramolecular assemblies 3 and 5, respectively. Crystallographic analyses reveal that they are stabilized by cooperative noncovalent interactions involving multiple hydrogen-bonding and π−π interactions.