sorry, we can't preview this file

...but you can still download (5.03 kB)

Selective Formic Acid Dehydrogenation Catalyzed by Fe-PNP Pincer Complexes Based on the 2,6-Diaminopyridine Scaffold

Download (5.03 kB)
posted on 22.09.2016 by Irene Mellone, Nikolaus Gorgas, Federica Bertini, Maurizio Peruzzini, Karl Kirchner, Luca Gonsalvi
Fe­(II) hydrido carbonyl complexes supported by PNP pincer ligands based on the 2,6-diaminopyridine scaffold were studied as homogeneous, non-precious-metal-based catalysts for selective formic acid dehydrogenation to hydrogen and carbon dioxide, reaching quantitative yields and high TONs under mild reaction conditions.