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Selective Formic Acid Dehydrogenation Catalyzed by Fe-PNP Pincer Complexes Based on the 2,6-Diaminopyridine Scaffold

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posted on 22.09.2016, 18:19 by Irene Mellone, Nikolaus Gorgas, Federica Bertini, Maurizio Peruzzini, Karl Kirchner, Luca Gonsalvi
Fe­(II) hydrido carbonyl complexes supported by PNP pincer ligands based on the 2,6-diaminopyridine scaffold were studied as homogeneous, non-precious-metal-based catalysts for selective formic acid dehydrogenation to hydrogen and carbon dioxide, reaching quantitative yields and high TONs under mild reaction conditions.