sorry, we can't preview this file
...but you can still download om800364b_si_004.cif
Selective Assembly of Trinuclear Rare-Earth Alkyl Hydrido Clusters Supported by Amidopyridinate Ligands
datasetposted on 14.07.2008 by Dmitrii M. Lyubov, Christian Döring, Georgii K. Fukin, Anton V. Cherkasov, Andrei S. Shavyrin, Rhett Kempe, Alexander A. Trifonov
Datasets usually provide raw data for analysis. This raw data often comes in spreadsheet form, but can be any collection of data, on which analysis can be performed.
The reactions of the bis(alkyl) complexes [Ap*Ln(CH2SiMe3)2(thf)] (Ln = Y, Lu) with both PhSiH3 and H2 result in selective assembly of the novel trinuclear rare-earth alkyl hydrido clusters [(Ap*Ln)3(μ2-H)3(μ3-H)2(CH2SiMe3)(thf)2]. Both cluster compounds are single-component ethylene polymerization catalysts.