ic2021808_si_002.cif (234.97 kB)
Ru–OSO Coordination Photogenerated at 100 K in Tetraammineaqua(sulfur dioxide)ruthenium(II) (±)-Camphorsulfonate
dataset
posted on 2012-02-06, 00:00 authored by Anthony
E. Phillips, Jacqueline M. Cole, Thierry d’Almeida, Kian Sing LowThe photoinduced O-bound coordination mode in RuSO2 complexes,
previously observed only at 13 K, has been generated at 100 K in tetraammineaqua(sulfur
dioxide)ruthenium(II) (±)-camphorsulfonate. This coordination
state, often denoted MS1, decays to the η2-bound
MS2 state, with an estimated half-life of 3.4(8) h and a long-lived
population of 2.9(4)% at 120 K.