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Ring-Opening Reactions of Difluoro(methylene)cyclopropanes with Halogens and Amines

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posted on 07.11.2008, 00:00 authored by Xiao-Chun Hang, Qing-Yun Chen, Ji-Chang Xiao
The distal and proximal bond of difluoro(methylene)cyclopropanes (F2MCPs) could be cleaved, respectively, under different conditions to give the corresponding ring-opening products. The reaction mechanisms are discussed.