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Rhodium Phosphinates as Catalysts for Metal-Stabilized Carbene Chemistry:  Synthesis, Characterization, and Application of Rh2(O2PMe2)4

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posted on 02.01.2006, 00:00 by George M. Adjabeng, David A. Gerritsma, Hitesh Bhanabhai, Christopher S. Frampton, Alfredo Capretta
The first rhodium(II) phosphinate complex, Rh2(O2PMe2)4, is described and is shown to act as an effective catalyst for the decomposition of α-diazo compounds.