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Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzooxasilines via Enantioselective Transmetalation

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posted on 2012-10-17, 00:00 authored by Ryo Shintani, Eleanor E. Maciver, Fumiko Tamakuni, Tamio Hayashi
A rhodium-catalyzed asymmetric synthesis of silicon-stereogenic dibenzooxasilines has been developed. High enantioselectivities have been achieved by employing (S,S)-Me-Duphos as the ligand through “enantioselective transmetalation”.