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Reactivity of the Dinuclear Arylstibonic Acid [2,6-Mes2C6H3Sb(O)(OH)2]2 toward H2SO4 and NaOH

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posted on 2009-04-13, 00:00 authored by Jens Beckmann, Malte Hesse
The syntheses are reported of the molecular arylantimony oxo compounds [(2,6-Mes2C6H3Sb)2(O)(OH)4SO4] (1) and [Na2(2,6-Mes2C6H3Sb)4O4(OH)10·2H2O] (2), which were obtained by the reaction of the dinuclear stibonic acid [2,6-Mes2C6H3Sb(O)(OH)]2 with aqueous H2SO4 and NaOH, respectively. The molecular structures of 1 and 2 were established by X-ray crystallography.

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