ja5b06627_si_003.cif (126.59 kB)
Download fileReactions of Titanium Hydrazides with Silanes and Boranes: N–N Bond Cleavage and N Atom Functionalization
dataset
posted on 19.08.2015, 00:00 authored by Laura
C Stevenson, Simona Mellino, Eric Clot, Philip MountfordReaction of Ti(N2iPrN)(NNPh2)(py) with Ph(R)SiH2 (R = H, Ph) or 9-BBN gave reductive
cleavage of the Nα–Nβ bond
and formation of new silyl- or boryl-amido ligands. The corresponding
reactions of Cp*Ti{MeC(NiPr)2}(NNR2) (R = Me or Ph) with HBPin or 9-BBN gave borylhydrazido-hydride
or borylimido products, respectively. Nα and Nβ atom transfer and dehydrogenative coupling reactions
are also reported.