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Reactions of Pyridyl Side-Chain-Functionalized Cyclopentadienes with Metal Carbonyl: Intramolecular C−H Activation of Pyridine

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posted on 2006-01-02, 00:00 authored by Dafa Chen, Ying Li, Baiquan Wang, Shansheng Xu, Haibin Song

Thermal treatment of the pyridyl side-chain-functionalized cyclopentadienes with Fe(CO)₅ and Ru₃(CO)₁₂ gave different intramolecular C−H activated products, in addition to the normal dinuclear metal complexes. Reactions of the dinuclear metal complexes with I₂ also gave different metal iodide complexes.