Re(I)-Catalyzed Hydropropargylation of Silyl Enol Ethers Utilizing Dynamic Interconversion of Vinylidene–Alkenylmetal Intermediates via 1,5-Hydride Transfer
datasetposted on 12.06.2018 by Nobuharu Iwasawa, Shoya Watanabe, Akane Ario, Hideyuki Sogo
Datasets usually provide raw data for analysis. This raw data often comes in spreadsheet form, but can be any collection of data, on which analysis can be performed.
Re(I)-catalyzed hydropropargylation reaction of silyl enol ethers was realized utilizing dynamic interconversion of vinylidene–alkenylmetal intermediates, where alkenylmetals underwent 1,5-hydride transfer of the α-hydrogen to generate vinylidene intermediates. Furthermore, this process was found to be in an equilibrium.