Rare Oxidation-State Combinations and Unusual Structural Motifs in Hexanuclear Mn Complexes Using 2-Pyridyloximate Ligands

dataset

posted on 2010-05-17, 00:00 authored by Constantinos C. Stoumpos, Ross Inglis, Olivier Roubeau, Harikleia Sartzi, Alexandros A. Kitos, Constantinos J. Milios, Guillem Aromí, Anastasios J. Tasiopoulos, Vasilios Nastopoulos, Euan K. Brechin, Spyros P. Perlepes

The use of phenyl-2-pyridyl ketone oxime and di-2-pyridyl ketone oxime in Mn chemistry has led to hexanuclear clusters with unprecedented (Mn^II₄Mn^IIIMn^IV) or extremely rare (Mn^IIMn^III₅ and Mn^II₃Mn^III₃) metal oxidation-state combinations and uncommon structural motifs.

History

Usage metrics

Keywords

motif Mn chemistry oxime Pyridyloximate combination Combination hexanuclear clusters Rare MnIIMnIII 5 di phenyl 3MnIII Unusual Structural Motifs Hexanuclear Mn Complexes MnII 4MnIIIMnIV ketone LigandsThe

Licence

CC BY-NC 4.0

Rare Oxidation-State Combinations and Unusual Structural Motifs in Hexanuclear Mn Complexes Using 2-Pyridyloximate Ligands

History

Usage metrics

Categories

Keywords

Licence

Exports