ol1005455_si_002.cif (18.14 kB)

Radical Amination with Trimethylstannylated Benzophenone Imine

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posted on 07.05.2010, 00:00 by Marie-Céline Lamas, Santiago E. Vaillard, Birgit Wibbeling, Armido Studer
Intermolecular radical amination reactions of various primary, secondary, and tertiary alkyl radicals by using trimethylstannylated benzophenone imine A as a novel radical acceptor to provide imines of type B are described. These imines are readily reduced with NaBH4 to the corresponding secondary amines C. The novel radical amination can be combined with typical radical cyclization reactions.