Pushing the Frontiers of Hard and Soft Scorpionate Chemistry
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posted on 2004-01-26, 00:00 authored by Christopher A. Dodds, Alan R. Kennedy, John Reglinski, Mark D. SpicerThe preparation and structure of the first scorpionate complex of
a group 16 element, [Te(κ<sup>2</sup>-Tm<sup>Me</sup>)<sub>2</sub>], is reported. It displays square
planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15
element, [Bi(Tp)<sub>2</sub>(pzH)Cl], has been synthesized and characterized.
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