American Chemical Society
Browse

Presynthesized and In-Situ Generated Tetrazolate Ligand in the Design of Chiral Cadmium Coordination Polymer

Download (17.65 kB)
dataset
posted on 2016-02-20, 15:55 authored by Che-Chi Chang, Yun-Chieh Huang, Sheng-Ming Huang, Jing-Yun Wu, Yen-Hsiang Liu, Kuang-Lieh Lu
In contrast to the in-situ generated 5-(4-pyridyl)­tetrazolate (4-ptz) ligand, the use of presynthesized 4-ptz led to the formation of a chiral cadmium coordination polymer with a rare μ5-bridging mode of the tetrazolate ligand. This type of tuning in the design of chiral coordination polymers is reported for the first time.

History