posted on 2016-02-20, 15:55authored byChe-Chi Chang, Yun-Chieh Huang, Sheng-Ming Huang, Jing-Yun Wu, Yen-Hsiang Liu, Kuang-Lieh Lu
In contrast to the in-situ generated 5-(4-pyridyl)tetrazolate
(4-ptz)
ligand, the use of presynthesized 4-ptz led to the formation of a
chiral cadmium coordination polymer with a rare μ5-bridging mode of the tetrazolate ligand. This type of tuning in
the design of chiral coordination polymers is reported for the first
time.