Preparation of NHC Borane Complexes by Lewis Base Exchange with Amine− and Phosphine−Boranes
datasetposted on 15.10.2010, 00:00 by Malika Makhlouf Brahmi, Julien Monot, Marine Desage-El Murr, Dennis P. Curran, Louis Fensterbank, Emmanuel Lacôte, Max Malacria
Datasets usually provide raw data for analysis. This raw data often comes in spreadsheet form, but can be any collection of data, on which analysis can be performed.
A versatile new method for the preparation of NHC boranes starting from two stable, readily available reactants―an heterocyclic salt and an amine or phosphine−borane―is reported. It uses a Lewis base exchange at boron and provides easy access to new NHC boranes, in particular B-substituted borane ones.