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Phosphonium-Templated Iodoplumbates

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posted on 2018-12-11, 19:25 authored by Emily H. Omahen, Justin F. Binder, Brad F. Jacobs, Ala’aeddeen Swidan, Charles L. B. Macdonald
A new family of iodoplumbates based on phosphonium cations have been synthesized and characterized via X-ray crystallography. Thermogravimetric analysis demonstrates that these materials have a remarkably high thermal stability and show potential for applications as organic–inorganic hybrid semiconductors. We also present the synthesis of three novel phosphonium salts and the crystallographic elucidation of these compounds.