Performance Improvement of Methane oxy-MILD Combustion
with High Initial Oxygen Contents Using a Novel Non-premixed Oxygen/Recycled
Flue Gas Jet Burner
posted on 2024-02-06, 07:29authored byShunta Xu, Ziyi Tian, Qunkang Dou, Yaojie Tu, Yu Fu, Hao Liu
Oxy-fuel moderate or intense low-oxygen
dilution (oxy-MILD) combustion
is a promising technology to control NOx emissions while achieving large-scale CO2 capture in
gas-fired industrial furnaces. However, oxy-MILD combustion still
presents challenges at high initial oxygen levels, where less satisfactory
thermal uniformity and even high NOx emissions
may occur. To address these challenges, this paper reports a novel
non-premixed oxygen/recycled flue gas (O2/RFG) jet burner,
whose novelty lies in that O2 and RFG are separately supplied
(where RFG serves as a “barrier gas” between fuel and
oxygen jets to delay their mixing before reaction) rather than premixed
with each other conventionally. Meanwhile, an improved GRI-Mech 3.0
model is proposed to predict prompt-NO formation via the NCN pathway
more accurately by adding the NCN, HNCN, and HNC reaction subsets.
Using the improved GRI-Mech 3.0 model, the performances of the non-premixed
O2/RFG jet burner and its difference from those of the
premixed one during methane oxy-MILD combustion are evaluated at different
oxygen concentrations of 25–35 vol % in a laboratory-scale
furnace. In particular, NO formation and reduction via thermal, prompt,
N2O-intermediate, NNH, and reburning pathways are revealed
in addition to combustion and heat transfer characteristics. Results
show that, compared to the premixed one, the non-premixed O2/RFG jet burner can sustain oxy-MILD combustion at a higher initial
oxygen level, where better temperature/heat flux uniformity is obtained
in a larger reaction zone. What’s more, NO emissions can be
reduced by 14.8–64.9% if air leakage occurs, mainly due to
less NO formation via N2 + O → NO and N2O + H/O → NO in the thermal and N2O-intermediate
pathways; also, the efficiency of NO reduction via HCCO/CHi=0–3 + NO reactions is enhanced by 2.3–8.6%
when doping 100–800 ppm of NO in the oxidizer. In conclusion,
the non-premixed O2/RFG jet burner is recommended to be
used to help establish/sustain oxy-MILD combustion at high initial
oxygen levels in industrial furnaces, where further NO emission reduction
can be achieved while improving thermal uniformity.