Oxidative 1,2-Difunctionalization of Ethylene via Gold-Catalyzed Oxyarylation
datasetposted on 22.08.2017, 00:00 by Matthew J. Harper, Edward J. Emmett, John F. Bower, Christopher A. Russell
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Under the conditions of oxidative gold catalysis, exposure of ethylene to aryl silanes and alcohols generates products of 1,2-oxyarylation. This provides a rare example of a process that allows catalytic differential 1,2-difunctionalization of this feedstock chemical.