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One-Dimensional Ferromagnetic Complexes Built with MnIII3O Units

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posted on 26.06.2006, 00:00 by Jun Tao, Yuan-Zhu Zhang, Yue-Lin Bai, Osamu Sato
Two chain complexes built with non-carboxylate MnIII3O units, [Mn3O(ppz)3(MeOH)3(OAc)]n (1) and [Mn3O(Meppz)3(MeOH)4(OAc)]n (2), were synthesized and characterized. Magnetic studies revealed similar intrachain ferromagnetic interactions in them and field-induced metamagnetic properties in 1.