ic049530c_si_002.cif (58.09 kB)

Octanuclear Metallocyclic Ni4Fc4 Compound:  Synthesis, Crystal Structure, and Electrochemical Sensing for Mg2+

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posted on 23.08.2004, 00:00 by Mingxue Li, Ping Cai, Chunying Duan, Feng Lu, Jin Xie, Qingjin Meng
New, neutral octanuclearmacrocyclic compound Ni4Fc4 was achieved via self-assembly from Ni(BF4)2 and a ferrocene-containing bis-tridentate ligand. The compound exhibits a channeled structure with cavities inside and senses the Mg2+ electrochemically in the solid state.