posted on 2020-02-06, 23:29authored byWei Huang, Yongxing Tang, Gregory H. Imler, Damon A. Parrish, Jean’ne M. Shreeve
Two metal-free explosives, tetrazolo[1,5-b]pyridazine-containing
molecules [6-azido-8-nitrotetrazolo[1,5-b]pyridazine-7-amine
(3at) and 8-nitrotetrazolo[1,5-b]pyridazine-6,7-diamine
(6)], were obtained via straightforward two-step synthetic
routes from commercially available reagents. Compound 3at displays an excellent detonation performance (Dv = 8746 m s–1 and P = 31.5 GPa) that is superior to commercial primary explosives such
as lead azide and diazodinitrophenol (DDNP). Compound 6 has superior thermal stability, remarkable insensitivity, and good
detonation performance, strongly suggesting it as an acceptable secondary
explosive. The initiating ability of compound 3at has
been tested by detonating 500 mg of RDX with a surprisingly low minimum
primary charge of 40 mg. The extraordinary initiating power surpasses
conventional primary explosives, such as commercial DDNP (70 mg) and
reported 6-nitro-7-azido-pyrazol[3,4-d][1,2,3]triazine-2-oxide
(ICM-103) (60 mg). The outstanding detonation power of 3at contributes to its future prospects as a promising green primary
explosive. In addition, the environmentally benign methodology for
the synthesis of 3at effectively shortens the time from
laboratory-scale research to practical applications.