ja8b05680_si_003.cif (352 kB)

Nickel-Catalyzed Stereoselective Diarylation of Alkenylarenes

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posted on 20.08.2018, 17:21 by Pin Gao, Liang-An Chen, M. Kevin Brown
A three-component coupling of aryl bromides, arylboron reagents, and alkenylarenes is presented. The method tolerates a variety of substitution patterns on all of the components. In particular, 1,2-disubstituted alkenylarenes are suitable and undergo highly diastereoselective diarylation.