ol5b00779_si_006.cif (32.02 kB)

New “Pyrene Box” Cages for Adaptive Guest Conformations

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posted on 01.05.2015, 00:00 by Dan Dumitrescu, Florina Dumitru, Yves-Marie Legrand, Eddy Petit, Arie van der Lee, Mihail Barboiu
The possibility of controlling the compression extent and the coiling shape of the 1,12-diammoniumdodecane guest is shown by changing the dimensions of the internal space of the host guanidinium 1,3,5,8 pyrene-tetrasulfonate PTS4– crystalline capsules by using guanidinium (G+), amino-guanidinium (AG+), and diaminoguanidinium (A2G+) cations.