jo071072c_si_015.cif (18.97 kB)
New Preparation of 1,2,4,5,7,8-Hexaoxonanes
dataset
posted on 2007-09-14, 00:00 authored by Alexander O. Terent'ev, Maxim M. Platonov, Eduard J. Sonneveld, Rene Peschar, Vladimir V. Chernyshev, Zoya A. Starikova, Gennady I. NikishinA new versatile procedure was developed for the synthesis of 1,2,4,5,7,8-hexaoxonanes based on the
Lewis acid catalyzed reaction of acetals with 1,1‘-dihydroperoxydicycloalkyl peroxides. The procedure
substantially extends the structural diversity of these compounds and, in most cases, allows the synthesis
of these compounds in higher yields (to 96%) and with higher selectivity. Complexation of hexaoxonane
with chloroform was documented for the first time. The structures of several triperoxides were established
by X-ray diffraction.