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New Preparation of 1,2,4,5,7,8-Hexaoxonanes

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posted on 14.09.2007, 00:00 by Alexander O. Terent'ev, Maxim M. Platonov, Eduard J. Sonneveld, Rene Peschar, Vladimir V. Chernyshev, Zoya A. Starikova, Gennady I. Nikishin
A new versatile procedure was developed for the synthesis of 1,2,4,5,7,8-hexaoxonanes based on the Lewis acid catalyzed reaction of acetals with 1,1‘-dihydroperoxydicycloalkyl peroxides. The procedure substantially extends the structural diversity of these compounds and, in most cases, allows the synthesis of these compounds in higher yields (to 96%) and with higher selectivity. Complexation of hexaoxonane with chloroform was documented for the first time. The structures of several triperoxides were established by X-ray diffraction.