New Crystalline Layered Zinc Phosphate with 10-Membered-Ring Channels Perpendicular to Layers
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posted on 2009-06-01, 00:00 authored by Lei Liu, Stanislav Ferdov, Cristina Coelho, Ying Kong, Luís Mafra, Jin P. Li, Jin X. Dong, Uwe Kolitsch, Rute A. Sá Ferreira, Ekkehart Tillmanns, João Rocha, Zhi LinA novel layered zinc phosphate, [N<sub>2</sub>C<sub>6</sub>H<sub>12</sub>]<sub>2</sub>[Zn<sub>7</sub>H<sub>3</sub>(HPO<sub>4−<i>x</i></sub>)<sub>5</sub>(PO<sub>4</sub>)<sub>3</sub>]H<sub>2</sub>O, with unique 10-membered-ring ellipsoidal channels running perpendicularly to ladder-shaped tetrahedral layers, has been synthesized ionothermally via in situ generation of 1,4-diazabicyclo[2.2.2]octane.
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