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Molecular Doping of Porous Organic Cages

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posted on 28.09.2011, 00:00 authored by Tom Hasell, Marc Schmidtmann, Andrew I. Cooper
Porous organic cages can act as hosts for the three-dimensional alignment of guests such as halogens and organometallics. Porous single crystals are doped by vapor sublimation to produce diamondoid arrangements of guests such as I5 and OsO4, leading to marked conductivity enhancement in the case of I5.