ic102378u_si_001.cif (102.58 kB)

Mn21Dy Cluster with a Record Magnetization Reversal Barrier for a Mixed 3d/4f Single-Molecule Magnet

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posted on 17.01.2011, 00:00 by Constantina Papatriantafyllopoulou, Wolfgang Wernsdorfer, Khalil A. Abboud, George Christou
A high-oxidation-state MnIII,IV21DyIII cluster with an unusual structure is reported. It also possesses a record barrier to magnetization reversal for a 3d/4f single-molecule magnet (SMM) and provides insight into how the full benefit of lanthanides to the mixed 3d/4f SMM field might be realized.