posted on 2020-03-06, 13:40authored byTara I. Yacovitch, Conner Daube, Scott C. Herndon
Shipboard
measurements of offshore oil and gas facilities were
conducted in the Gulf of Mexico in February 2018. Species measured
at 1 s include methane, ethane, carbon-13 (13C) and deuterium
(D) isotopes of methane, and several combustion tracers. Significant
variability in the emission composition is observed between individual
sites, with typical ethane/methane ratios around 5.3% and 13C and D methane isotopic compositions around −40 and −240‰,
respectively. Offshore plumes were spatially narrower than expectations
of the plume width based on terrestrial atmospheric stability classes;
a modified Gaussian dispersion methodology using empirically measured
horizontal plume widths was used to estimate the emission rates. A
total of 103 sites were studied, including shallow and deepwater offshore
platforms and drillships. Methane emission rates range from 0 to 190
kg/h with 95% confidence limits estimated at a factor of 10. The observed
distribution is skewed with the top two emitters accounting for 20%
of the total methane emissions of all sampled sites. Despite the greater
throughput of the deepwater facilities, they had moderate emission
rates compared to shallow-water sites. Analysis of background ethane
enhancements also suggests a source region in shallow waters. A complete
1 s measurement database is published for use in future studies of
offshore dispersion.