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Magnesium Borohydride Complexed by Tetramethylethylenediamine

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posted on 14.05.2007, 00:00 authored by Grigorii L. Soloveichik, Matthew Andrus, Emil B. Lobkovsky
A complex of magnesium borohydride, Mg(BH4)2·Me2NC2H4NMe2, has been synthesized and structurally characterized. This monomer complex has a pseudotetrahedral geometry around the Mg atom with tridentate BH4 groups and short Mg···B distances.