American Chemical Society
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Ligand- and Anion-Directed Assembly of Exo-Coordinated Mercury(II) Halide Complexes with O2S2-Donor Macrocycles

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posted on 2008-03-17, 00:00 authored by So Young Lee, Sunhong Park, Hyun Jee Kim, Jong Hwa Jung, Shim Sung Lee
Assembly reactions of mercury(II) halides (Cl, Br, and I) with two O2S2 macrocycles (L1 and L2) having different interdonor (S···S) distances were investigated, and four types of supramolecular complexes (14b) were obtained depending on the S···S distances as well as the size of the halide anions. Photoluminescence of these compounds was also studied.