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Download fileLigand-Promoted Rh(III)-Catalyzed Coupling of Aryl C–H Bonds with Arylboron Reagents
dataset
posted on 2016-03-18, 00:00 authored by Huai-Wei Wang, Pei-Pei Cui, Yi Lu, Wei-Yin Sun, Jin-Quan YuRhodium(III)-catalyzed
C–H arylation of arenes with phenylboronic
acid pinacol esters has been achieved using a readily removable N-pentafluorophenylbenzamide directing group for the first
time. The use of a bidentate phosphine ligand (Binap) significantly
increased the yield of the cross-coupling of C–H bonds with
organoboron reagents.