ja509077a_si_001.cif (1.85 MB)

Ligand-Controlled Regiodivergent Ni-Catalyzed Reductive Carboxylation of Allyl Esters with CO2

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posted on 24.12.2014, 00:00 by Toni Moragas, Josep Cornella, Ruben Martin
A novel Ni-catalyzed regio­divergent reductive carboxylation of allyl esters with CO2 has been developed. This mild, user-friendly, and operationally simple method is characterized by an exquisite selectivity profile that is dictated by the ligand backbone.