om0600893_si_001.cif (17.71 kB)

Lewis Base Character of Hydroxygermylenes for the Preparation of Heterobimetallic LGe(OH)M Systems (M = Fe, Mn, L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3)

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posted on 24.04.2006, 00:00 by Leslie W. Pineda, Vojtech Jancik, Juan F. Colunga-Valladares, Herbert W. Roesky, Anja Hofmeister, Jörg Magull
LGeOH (1; L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) reacted with iron and manganese complexes to give LGe(OH)Fe(CO)4 (2) and LGe(OH)Mn(Cp)(CO)2 (3; Cp = cyclopentadienyl). Compounds 2 and 3 were characterized by IR, multinuclear NMR, EI-MS, and single-crystal X-ray diffraction.