om049907m_si_001.cif (18.67 kB)
Isolation of Bis(η2-nitrato)(η4-cyclobutadiene)cobalt(II) Complexes from the Oxidation of Sterically Hindered CpCo-Stabilized Cyclobutadiene Complexes
dataset
posted on 2004-05-10, 00:00 authored by Carsten Schaefer, Rolf Gleiter, Frank RomingerThe oxidation of sterically hindered, CpCo-protected cyclobutadienes with ceric ammonium nitrate
(CAN) yielded the paramagnetic Co(NO3)2-protected
cyclobutadiene products. These half-sandwich complexes
represent possible intermediates within the mechanism
of the CAN decomplexation of CpCo−cyclobutadiene
complexes.