jo9b02199_si_002.cif (409 kB)

Iodine-Catalyzed Selenylation of 2H‑Indazole

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posted on 25.10.2019, 11:03 by Amrita Dey, Alakananda Hajra
A metal-free, environmentally friendly protocol for the arylselenylation of 2H-indazole has been developed using a catalytic amount of I2 under ambient conditions. A number of 3-(phenylselanyl)-2H-indazoles with wide functional group tolerance have been synthesized in good yields at room temperature. Mechanistic studies suggest that the reaction possibly proceeds through an ionic pathway.