ic901143h_si_003.cif (72.59 kB)

Indium Chalcogenido Clusters Coordinated by 1,10-Phenanthroline, [InQ(phen)Cl]4 (Q = Se, S), a Simplified Model of Inorganic−Organic Hybrid Material with Cluster-to-Ligand Charge Transfer

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posted on 18.01.2010, 00:00 by Zhi-Xin Lei, Qin-Yu Zhu, Ming-Hui Zhang, Jian-Bing Jiang, Ya-Ping Zhang, Jie Dai
Most metal−1,10-phenanthroline-complex-sensitized inorganic semiconductors are multicomponent materials. This fundamental study was devoted to the single-phase materials fused with moieties of the phen complex and inorganic chalcogenide. Compounds 1 and 2 are new types of cubic clusters with cluster-to-ligand charge transfer.