American Chemical Society
cg801267m_si_001.cif (20.84 kB)

Highly Tunable Heterometallic Frameworks Constructed from Paddle-Wheel Units and Metalloporphyrins

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posted on 2009-04-01, 00:00 authored by Paul M. Barron, Hyun-Tak Son, Chunhua Hu, Wonyoung Choe
Seven new heterometallic frameworks have been synthesized with specific control over the metallic composition of each structure. Using Mn, Fe, Ni, V, and Pt metallated tetra-(4-carboxyphenyl)porphine (MTCPP) metalloligands and Zn and Co paddle-wheel building units, two series of heterometallic frameworks are assembled that maintain topology with changing metal composition.