High-Temperature Spin Crossover in a Mononuclear Six-Coordinate Cobalt(II) Complex
dataset
posted on 2014-10-06, 00:00 authored by Joanna Palion-Gazda, Anna Świtlicka-Olszewska, Barbara Machura, Thais Grancha, Emilio Pardo, Francesc Lloret, Miguel JulveThe six-coordinate cobalt(II) complex
of formula [Co(tppz)<sub>2</sub>](tcm)<sub>2</sub> exhibits a thermally
induced spin-crossover behavior from a high spin (<i>S</i> = <sup>3</sup>/<sub>2</sub>) at higher temperatures to a low spin
(<i>S</i> = <sup>1</sup>/<sub>2</sub>) at lower temperatures,
with the low-spin phase being achieved at <i>T</i> ≤
200 K.
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