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Hexanuclear Platinum(II) Thiolate Macrocyclic Host: Charge-Transfer-Driven Inclusion of a AgI Ion Guest

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posted on 08.09.2016, 13:18 by Yukatsu Shichibu, Keisuke Yoshida, Katsuaki Konishi
The inclusion of a AgI ion by a hexanuclear platinum­(II) thiolate macrocycle in solution was demonstrated, and the inclusion structure was determined by X-ray crystallography. Unique host–guest intermetallic interactions driven by charge transfer were elucidated by optical absorption spectroscopy and theoretical calculations.