ja0561439_si_004.cif (15.72 kB)
Download file

Guest-Induced Asymmetry in a Metal−Organic Porous Solid with Reversible Single-Crystal-to-Single-Crystal Structural Transformation

Download (15.72 kB)
posted on 14.12.2005, 00:00 by Tapas Kumar Maji, Golam Mostafa, Ryotaro Matsuda, Susumu Kitagawa
A metal−organic honeycomb-like 2D pillared-bilayer open framework has been constructed which shows dynamic sponge-like single-crystal-to-single-crystal transformation upon dehydration and rehydration. The dehydrated acentric nonporous phase transformed to the porous centric phase with the selective adsorbate concomitant with the structural transformation correlated with the single-crystal structure determination.